Volume 383
Main Index

Issues 1-3, Pages C1-C14, 1-602 (20 February 1990)

Action of Carbon Monoxide on Nickel Pages 1-5 L. Mond, C. Langer, F. Quincke

The History of My Process of Nickel Extraction Pages 7-10 L. Mond

Ludwig Mond — father of metal carbonyls — and so much more (7 March 1839–11 December 1909) Pages 11-20 Edward Abel

100 years of metal carbonyls: a serendipitous chemical discovery of major scientific and industrial impact Pages 21-44 Wolfgang A. Herrmann

Electron-transfer processes with substituted group 5 metal carbonyls. Synthesis, crystal and molecular structure of Ag3M3(CO)12(Me2PCH2CH2PMe2)3, M = Nb, Ta, the first structurally characterized carbonyl derivatives of niobium(0) and tantalum(0) Pages 45-57 Fausto Calderazzo, Guido Pampaloni, Ullrich Englert, Joachim Strähle

Ligand and metal effects on the reactivity of metal carbonyls Pages 59-69 Jim D. Atwood

Binuclear vanadium complexes containing sulfur and selenium ligands: The reactions of the half-sandwich compounds CpV(CO)4 and CpV(CO)4 with dichalcogenides E2R2 (E = S, Se; R = Me, Ph). The X-ray crystallographic structures of Cp2V2(CO)4(μ-SR)2 (R = Me, Ph; Cp = C5Me5) Pages 71-84 Max Herberhold, Markus Kuhnlein, Walter Kremnitz, Arnold L. Rheingold

Arenetricarbonylchromium complexes in the synthesis of 6,7-benzomorphanes Pages 85-91 V.N. Kalinin, S.K. Moiseev, V.I. Bakhmutov, I.A. Cherepanov

Carbene ligands as anthracyclinone synthons VII. Quinone ketal functionalized carbonyl carbene complexes: Synthesis, structure and carbene annulation Pages 93-111 Karl Heinz Dötz, Michael Popall, Gerhard Müller, Klaus Ackermann

Synthesis of cationic π-complexes of transition metals of groups VI–VIII by exchange of the carbonyl ligands in strong protonic acids Pages 113-123 M.I. Rybinskaya

Der kohlenmonoxidligand als baustein für alkenylketonverbindungen Pages 125-142 Helmut G. Alt

Pseudohalogeno-metallverbindungen LXXII. Addition des azid-ions und anderer N-nucleophile an koordinierte kohlenmonoxid- und CO-ähnliche liganden und verwandte reaktionen. Azido- und isocyanato-carbonyl-metallkomplexe Pages 143-160 Wolfgang Beck

Controlling the regiochemistry of nucleophilic attack on unsymmetrical allyl complexes Pages 161-177 J.W. Faller, C. Lambert, M.R. Mazzieri

Übergangsmetal-Carbin-Komplexe: XCVI. Erste carbonylfreie, neutrale und kationische Phenylcarbin-Komplex von Wolfram mit Isonitril-Liganden Pages 179-190 Alexander Constantin Filippou, Ernst Otto Fischer

Reactions of anionic transition metal carbonyl hydrides with electrophilic metal carbonyls: Nucleophilic addition (hydride transfer) vs. electron transfer mechanisms Pages 191-199 Marcetta Y. Darensbourg, Carlton E. Ash, Larry W. Arndt, Christopher P. Janzen, Kay A. Youngdahl, Yong K. Park

Protonolysis reactions in the series RMn(CO)5 and RC(O)Mn(CO)5 Pages 201-212 Philip L. Motz, Daniel J. Sheeran, Milton Orchin

Optical resolution and absolute configuration of the chiral pentamethylcyclopentadienylrhenium carbonyl complex [(η5-C5Me5)Re(NO)(PPh3)(CO)]+ BF4− Pages 213-225 Yo-Hsin Huang, Francine Niedercorn, Atta M. Arif, J.A. Gladysz

Synthetic and structural studies on (η5:η5-fulvalene)bimetallic compounds derived from (η5:η5-fulvalene)dithallium Pages 227-252 Marvin D. Rausch, W.Craig Spink, Brian G. Conway, Robin D. Rogers, Jerry L. Atwood

The syntheses, structures, and stereodynamics of [3]-ferrocenophane complexes III. Rhenium tricarbonyl halide complexes, fac-[ReX(CO)3(C5H4ECH3)2Fe] (X = Cl, Br, I; E = S, Se). Crystal structure of chloro-1,1′-bis(methylthio)ferrocenetricarbonylrhenium Pages 253-269 Edward W. Abel, Nicholas J. Long, Keith G. Orrell, Anthony G. Osborne, Vladimir Šik, Paul A. Bates, Michael B. Hursthouse

Electrochemical studies of an oxidatively induced ring slippage in 17-electron (η3-indenyl)(η5-indenyl)V(CO)2 Pages 271-278 Glenn A. Miller, Michael J. Therien, William C. Trogler

Chemistry of carbonyl-derived ligands. Nucleophilic attack on anionic acetylide clusters Pages 279-294 Michael P. Jensen, Michal Sabat, Dean H. Johnston, Lisa M. Jones, Duward F. Shriver

Formation and chemical reactivity of metal carbonyl complexes containing phosphorus-bridging carbonyl groups Pages 295-305 R.B. King, F.-J. Wu, E.M. Holt

Preparation and reactions of tricarbonyl(3-trimethylstannylcycloheptadienyl)iron hexafluorophosphate and tricarbonyl(3-trimethylsilylcycloheptadienyl)iron hexafluorophosphate Pages 307-319 Anthony J. Pearson, Michael S. Holden

Cyclopentadienyl thiocarbonyl complexes of iron: [CpFe(CO)2CS]+, Cp2Fe2(CO)2(CS)2, Cp2Fe2(CO)3(CS), and Cp2Fe2(CO)2(CS)2 Pages 321-337 Moon-Gun Choi, Lee M. Daniels, Robert J. Angelici

Quantitative mechanistic studies of the photoreactions of trinuclear metal carbonyl clusters of iron, ruthenium and osmium Pages 339-356 Peter C. Ford

Carbonyl ligands from alkynes: oxidative decarbonation of acetylide bridged complexes Pages 357-366 Wolfgang Bernhardt, Heinrich Vahrenkamp

Syntheses and structures of methyl-, acetyl- and allyl-ruthenium carbidocarbonyl clusters Pages 367-385 Teiji Chihara, Katsuyuki Aoki, Hiroshi Yamazaki

Tetranuclear carbonyls of osmium Pages 387-411 Roland K. Pomeroy

Synthesis and reactions of edge double-bridged trinuclear cluster complexes of ruthenium or osmium Pages 413-420 Herbert D. Kaesz

Syntheses and structures of rhodium-osmium clusters derived from the reaction of (μ-H)2Os3(CO)10 with (η5-C5H5)Rh(CO)2 Pages 421-440 Anne Colombie, Deborah A. McCarthy, Jeanette Krause, Leh-Yeh Hsu, Wen-Liang Hsu, Deng-Yang Jan, Sheldon G. Shore

Carbide forming and cluster build-up reactions in ruthenium carbonyl cluster chemistry Pages 441-461 Philip J. Bailey, M.J. Duer, Brian F.G. Johnson, Jack Lewis, Grainne Conole, Mary McPartlin, Harold R. Powell, Christopher E. Anson

Ruthenium-platinum carbonyl cluster complexes with bridging methylene, methylidyne, and carbido ligands; crystal structures of the compounds [Ru2Pt(μ-CH2)(μ-CO)(CO)2{P(cyclo-C6H11)3}(η-C5H5)2], [Ru2Pt2(μ-H)(μ4-CH)(μ-CO)(CO)2(PPr3i)2(η-C5H5)2], and [Ru2Pt2(μ-H)2(μ4-C)(μ-CO)2(PPr3i)2(η-C5H5)2] Pages 463-480 David L. Davies, John C. Jeffery, Daniel Miguel, Paul Sherwood, F.Gordon A. Stone

Carbonyl-η-hexamethylbenzene complexes of osmium. Carbon-hydrogen activation by (η-C6Me6)Os(CO)(H)2 Pages 481-496 William A. Kiel, Richard G. Ball, William A.G. Graham

The photochemistry of dinuclear osmium carbonyl complexes; characterisation of Os2(CO)8 using matrix isolation Pages 497-519 Anthony Haynes, Martyn Poliakoff, James J. Turner, Bruce R. Bender, Jack R. Norton

Highly reduced organometallics XXVII. Synthesis, isolation and characterization of trisodium tricarbonylcobaltate(3 -), and initial studies on its derivative chemistry Pages 521-530 John E. Ellis, Paul T. Barger, Mark L. Winzenburg, Garry F. Warnock

Reaction kinetics of some substituted tetrarhodium carbonyl clusters Pages 531-542 Nancy M.J. Brodie, Anthony J. Poë

Reactions of the [Ni6(CO)12]2- dianion with stibine and bismuthine reagents: synthesis and stereophysical characterization of the [Ni10(SbPh)2(CO)18]2- dianion containing a noncentered icosahedral Ni10Sb2 core and Ni2(CO)4(μ2-Ph2SbOSbPh2)2 containing a centrosymmetric eight-membered (NiSbOSb)2 ring Pages 543-572 Robert E. DesEnfants II, James A. Gavney Jr., Randy K. Hayashi, A.David Rae, Lawrence F. Dahl, Asgeir Bjarnason

Mild, regiospecific hydrocarboxylation of alkynes catalyzed by nickel cyanide under phase transfer conditions Pages 573-577 Ibrahim Amer, Howard Alper

Early kinetic studies on CO substitution reactions of metal carbonyls Pages 579-586 Fred Basolo

Protonation and alkylation of benzoyl(carbamoyl)-palladium(II) and -platinum(II) complexes to give cationic benzoyl complexes with O-protonated and O-alkylated carbamoyl ligands. Characterization of an intermediate in the reaction of trans-[Pd(COPh)(CO)(PMe3)2]BH4 with pyrrolidine to give trans-Pd(COPh)(COH2)(PMe3)2 Pages 587-601 Li Huang, Fumiyuki Ozawa, Kohtaro Osakada, Akio Yamamoto

Reactions of sodium pentacarbonylrhenate(1 —) with activated acetylenes. Formation of rhenacyclobutenone complexes Pages C1-C6 Laura L. Padolik, Judith Gallucci, Andrew Wojcicki

Author index Page C7

Subject index Pages C9-C13

Introduction Page V